Higher science & research (IIT JAM & CSIR NET)

IIT JAM & CSIR NET - Chemical Sciences previous year questions (PYQ)

31,128 previous year IIT JAM & CSIR NET - Chemical Sciences questions, grouped by year, with answers and solutions.

2026 (30300 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #399] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(B)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(C)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
(D)
H = T - V representing the total potential Lagrangian
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Q2.
[Organic Chemistry & Reaction Mechanisms Problem #22] Regarding eigenvalues of a real symmetric matrix A: Which of the following analytical formulations is correct?

(A)
Eigenvalues must always be positive integers
(B)
All eigenvalues are pure imaginary
(C)
All eigenvalues are strictly real, and eigenvectors from distinct eigenvalues are orthogonal
(D)
The matrix cannot be diagonalized under any orthogonal transformation
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2025 (72 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #134] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(B)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
(C)
H = T - V representing the total potential Lagrangian
(D)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #404] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n^2 ħ^2) / (8 m L^2)
(B)
E_n = (n + 1/2) ħ ω
(C)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(D)
E_n = ħ^2 k^2 / (4 m L)
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2024 (100 questions)

Q1.

Advanced Research & Methodology: In scholarly analysis of 'Chirality Optical Activity and Conformational Analysis', which methodological approach ensures reproducibility and minimizes systematic bias?

(A)

Controlled multi-factorial experimental design with blinded statistical validation (Chirality Optical Activity and Conformational Analysis)

(B)

Post-hoc selective data reporting highlighting only conforming sample sets

(C)

Uncalibrated qualitative impressions without standardized measurement criteria

(D)

Extrapolating microscopic laboratory observations directly to macro ecosystems without validation

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Q2.

Advanced Research & Methodology: In scholarly analysis of 'UV-Vis IR 1H-NMR and 13C-NMR Spectral Analysis', which methodological approach ensures reproducibility and minimizes systematic bias?

(A)

Controlled multi-factorial experimental design with blinded statistical validation (UV-Vis IR 1H-NMR and 13C-NMR Spectral Analysis)

(B)

Post-hoc selective data reporting highlighting only conforming sample sets

(C)

Uncalibrated qualitative impressions without standardized measurement criteria

(D)

Extrapolating microscopic laboratory observations directly to macro ecosystems without validation

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2023 (72 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #246] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n^2 ħ^2) / (8 m L^2)
(B)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(C)
E_n = (n + 1/2) ħ ω
(D)
E_n = ħ^2 k^2 / (4 m L)
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #195] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
(B)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(C)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(D)
H = T - V representing the total potential Lagrangian
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2022 (72 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #154] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
H = T - V representing the total potential Lagrangian
(B)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(C)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(D)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #314] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
(B)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(C)
H = T - V representing the total potential Lagrangian
(D)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
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2021 (72 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #182] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(B)
E_n = (n^2 ħ^2) / (8 m L^2)
(C)
E_n = ħ^2 k^2 / (4 m L)
(D)
E_n = (n + 1/2) ħ ω
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #141] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(B)
E_n = (n + 1/2) ħ ω
(C)
E_n = ħ^2 k^2 / (4 m L)
(D)
E_n = (n^2 ħ^2) / (8 m L^2)
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2020 (72 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #163] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = ħ^2 k^2 / (4 m L)
(B)
E_n = (n + 1/2) ħ ω
(C)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(D)
E_n = (n^2 ħ^2) / (8 m L^2)
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #129] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(B)
E_n = ħ^2 k^2 / (4 m L)
(C)
E_n = (n + 1/2) ħ ω
(D)
E_n = (n^2 ħ^2) / (8 m L^2)
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2019 (72 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #311] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
H = T - V representing the total potential Lagrangian
(B)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(C)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(D)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #398] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n + 1/2) ħ ω
(B)
E_n = (n^2 ħ^2) / (8 m L^2)
(C)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(D)
E_n = ħ^2 k^2 / (4 m L)
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2018 (74 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #492] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n + 1/2) ħ ω
(B)
E_n = (n^2 ħ^2) / (8 m L^2)
(C)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(D)
E_n = ħ^2 k^2 / (4 m L)
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #212] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = ħ^2 k^2 / (4 m L)
(B)
E_n = (n^2 ħ^2) / (8 m L^2)
(C)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(D)
E_n = (n + 1/2) ħ ω
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2017 (74 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #389] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n + 1/2) ħ ω
(B)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(C)
E_n = ħ^2 k^2 / (4 m L)
(D)
E_n = (n^2 ħ^2) / (8 m L^2)
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #389] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n + 1/2) ħ ω
(B)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
(C)
E_n = ħ^2 k^2 / (4 m L)
(D)
E_n = (n^2 ħ^2) / (8 m L^2)
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2016 (74 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #490] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(B)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(C)
H = T - V representing the total potential Lagrangian
(D)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #188] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
H = T - V representing the total potential Lagrangian
(B)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
(C)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
(D)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
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2015 (74 questions)

Q1.
[Physical Chemistry, Quantum & Thermodynamics Problem #455] Regarding energy eigenvalues of a particle of mass m in a 1D infinite potential well of width L: Which of the following analytical formulations is correct?

(A)
E_n = (n + 1/2) ħ ω
(B)
E_n = ħ^2 k^2 / (4 m L)
(C)
E_n = (n^2 ħ^2) / (8 m L^2)
(D)
E_n = (n^2 π^2 ħ^2) / (2 m L^2), where n = 1, 2, 3...
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Q2.
[Physical Chemistry, Quantum & Thermodynamics Problem #365] Regarding Hamiltonian formulation of classical mechanics: Which of the following analytical formulations is correct?

(A)
H = T - V representing the total potential Lagrangian
(B)
Hamilton's canonical equations are dq_i/dt = ∂H/∂p_i and dp_i/dt = -∂H/∂q_i
(C)
d/dt(∂L/∂q_dot) - ∂L/∂q = 0
(D)
dq_i/dt = -∂H/∂p_i and dp_i/dt = ∂H/∂q_i
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