Engineer & Medical

Alcohols Phenols and Ethe question bank (Chemistry)

Practice 220 free Engineer & Medical Chemistry - Alcohols Phenols and Ethe questions with answers and step-by-step solutions.

Q1.

An organic compound $\mathbf{P}$ having molecular formula $\mathrm{C}_6 \mathrm{H}_6 \mathrm{O}_3$ gives ferric chloride test and does not have intramolecular hydrogen bond. The compound $\mathbf{P}$ reacts with 3 equivalents of $\mathrm{NH}_2 \mathrm{OH}$ to produce oxime $\mathbf{Q}$. Treatment of $\mathbf{P}$ with excess methyl iodide in the presence of $\mathrm{KOH}$ produces compound $\mathbf{R}$ as the major product. Reaction of $\mathbf{R}$ with excess iso-butylmagnesium bromide followed by treatment with $\mathrm{H}_3 \mathrm{O}^{+}$gives compound $\mathrm{S}$ as the major product. The total number of methyl $\left(-\mathrm{CH}_3\right)$ group(s) in compound $\mathbf{S}$ is ________. (consider maximum value if there are two values)

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Q2.

In the following reactions, P,Q,R and S are the major products.

The correct statement about P,Q,R and S is

(A)
P is a primary alcohol with four carbons.
(B)
Q undergoes Kolbe's electrolysis to give an eight-carbon product.
(C)
R has six carbons and it undergoes Cannizzaro reaction.
(D)
S is a primary amine with six carbons.
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