Engineer & Medical

p Block Elements (Group 1 question bank (Chemistry)

Practice 2,207 free Engineer & Medical Chemistry - p Block Elements (Group 1 questions with answers and step-by-step solutions.

Q1.

Consider the following reactions.
$\mathrm{PbCl}_{2}+\mathrm{K}_{2} \mathrm{CrO}_{4} \rightarrow \mathrm{~A}+2 \mathrm{KCl}$
(Hot solution)
$\mathrm{A}+\mathrm{NaOH} \rightleftharpoons \mathrm{B}+\mathrm{Na}_{2} \mathrm{CrO}_{4}$
$\mathrm{PbSO}_{4}+4 \mathrm{CH}_{3} \mathrm{COONH}_{4} \rightarrow\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}+\mathrm{X}$
In the above reactions, $\mathrm{A}, \mathrm{B}$ and X are respectively.

(A)
\(\mathrm{Na}_2\left[\mathrm{~Pb}(\mathrm{OH})_2\right], \mathrm{PbCrO} \mathrm{O}_4\) and \(\left(\mathrm{NH}_4\right)_2\left[\mathrm{~Pb}\left(\mathrm{CH}_3 \mathrm{COO}\right)_4\right]\)
(B)
$\mathrm{Na}_{2}\left[\mathrm{~Pb}(\mathrm{OH})_{2}\right], \mathrm{PbCrO}_{4}$ and $\left[\mathrm{Pb}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{SO}_{4}$
(C)
$\mathrm{PbCrO}_{4}, \mathrm{Na}_{2}\left[\mathrm{~Pb}(\mathrm{OH})_{4}\right]$ and $\left(\mathrm{NH}_{4}\right)_{2}\left[\mathrm{~Pb}\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{4}\right]$
(D)
$\mathrm{PbCrO}_{4}, \mathrm{Na}_{2}\left[\mathrm{~Pb}(\mathrm{OH})_{4}\right]$ and $\left[\mathrm{Pb}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{SO}_{4}$
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Q2.

The group 14 elements A and B have the first ionisation enthalpy values of $708$ and $715 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively. The above values are lowest among their group members. The nature of their ions $\mathrm{A}^{2+}$ $\mathrm{B}^{4+}$ respectively is

(A)
both reducing
(B)
both oxidising
(C)
reducing and oxidising
(D)
oxidising and reducing
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