Initial pressure and volume of a monoatomic ideal gas are $P$ and $V$. The change in internal energy of this gas in adiabatic expansion to volume $V_{final}=27V$ is ________ J.
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One mole of diatomic gas having rotational modes only is kept in a cylinder with a piston system. The cross-section area of the cylinder is $4$ cm$^2$. The gas is heated slowly to raise the temperature by $1.2\,^\circ$C during which the piston moves by $25$ mm. The amount of heat supplied to the gas is ________ J. (Atmospheric pressure $=100$ kPa, $R=8.3$ J/mol·K) (Neglect mass of the piston)
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